Cover Feature: Photoelectrochemical CO 2 Reduction to Formate with the Sacrificial Reagent Free System of Semiconductor Photocatalysts and Formate Dehydrogenase (ChemCatChem 24/2019)
نویسندگان
چکیده
منابع مشابه
Protein engineering of formate dehydrogenase.
NAD+-dependent formate dehydrogenase (FDH, EC 1.2.1.2) is one of the best enzymes for the purpose of NADH regeneration in dehydrogenase-based synthesis of optically active compounds. Low operational stability and high production cost of native FDHs limit their application in commercial production of chiral compounds. The review summarizes the results on engineering of bacterial and yeast FDHs a...
متن کاملFormate dehydrogenase from Ralstonia eutropha
1 Spectroscopic and kinetic properties of the molybdenum-containing, NAD+-dependent formate dehydrogenase from Ralstonia eutropha. Dimitri Niks, Jayant Duvvuru, Miguel Escalona, and Russ Hille Department of Biochemistry, University of California, Riverside, Riverside, CA 92521 Running title: Formate dehydrogenase from Ralstonia eutropha To whom correspondence should be addressed: Prof. Russ Hil...
متن کاملSome properties of formate dehydrogenase.
In addition the enzyme catalyzes the oxidation of NADH by 0 2 . The stoichiometry of the first reaction is proved by the formation of the amount of NADH which under anaerobic conditions exactly corresponds to the amount of formate used. In this reaction NAD is replaceable by a large number of redox dyes. For the second reaction the stoichiometry is proved a) kinetically by the relation of the v...
متن کاملPurification and Characterization of Formate Dehydrogenase
Anaylobacter aguaticus strain KNK607M, which had high NAD-dependent formate dehydrogenase (FDH) activity, was newly isolated. The enzyme, purified to homogeneity, was a dimer composed of identical subunits with a molecular mass of 44 kDa. The specific activity was 9.5 ulmg, and the enzyme was optimum at pH 6.3 and 500C, most stabte at pH 7.0, and stable at 50"C or lovver. The apparent K. yalues...
متن کاملsynthesis of 3-aryl-2h-benzo[b]-1,4-oxazines in [omim]bf4 and reduction of organic compounds in methylimidazolium formate
در این پروژه ترکیبات 3-آریل-2h-بنزو[b]-4،1-اکسازین ها از مواد اولیه تجاری مشتقات دو آمینو فنول و ?-هالو کتون های آروماتیک در مایع یونی 1-اکتیل-3-متیل ایمیدازولیوم تترا فلورو بورات([omim]bf4) سنتز شده است. این واکنش توسط باز پتاسیم کربنات محلول از طریق o-آلکیلاسیون و سپس یک واکنش آمیداسیون درون مولکولی خود بخود در مدت زمان کوتاه انجام می شود. ترکیبات 4،1-بنزوکسازین به این روش با بهره خوب تا آلی ...
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ژورنال
عنوان ژورنال: ChemCatChem
سال: 2019
ISSN: 1867-3880,1867-3899
DOI: 10.1002/cctc.201902119